Btukfyl

I've seen chord progressions explained using chords looking like this.
https://www.musictheory.net/lessons/55

My question is why this voicing over say just a Root 3rd and 5th?
Is it just that it sounds better?

It doesn't sound inherently better or worse than the narrow root-3rd-5th voicing, just different. Somewhat palpably, a narrow-voiced chord will tend to sound intimate, focused, unitary, whereas a wide voicing will sound more open, dreamy or adventurous.

But the reason for a given voicing of one chord can usually not be reduced to just its sound as such, but to the musical context. In particular if you use only narrow chords in root position, you'll inevitably have a lot of big jumps in parallel movement. This can be used as a stylistic element; some guitarists just slide around one chord shape over the neck all of the time. But it sounds rather raw and unsophisticated.

Classical music and many styles after it strongly avoids this kind of parallel movement. In classical music, harmony isn't just understood as sequencing of chords but as a particular form of counterpoint between individual melodic voices. And this generally strives for smooth transitions with not too big jumps in each voice (unless as a deliberate effect), and tends to prefer contrary motion to parallel motion to “unglue” the voices. This is quite hard to do with only narrow voicings.

There are probably countless reasons why you might choose to voice a chord this way; some which come to mind are:

1. Intervals like the third sometimes sound a bit muddy in the bass register, therefore one might wish to have more space between the root and the third. See this question for more detail.

2. It may arise due to the needs of proper voice leading. Depending on what comes before and after this chord, this voicing may well make for the smoothest/most pleasing transition.

3. These kinds of voicings are also common in Chorale harmonizations (examples) which are commonly used as a tool for teaching harmony and voice leading (see above), which might be what that lesson is setting you up for. Chorale harmonizations are often written on piano staves (and played on keyboard instruments), but ultimately originate as vocal music which leads to making slightly different choices than one would make in music written with a keyboard instrument in mind.

4. As you say, one might feel that it sounds better. The most important factor when describing chord voicings is generally the bass note, as it determines which inversion is being played, but there's generally more leeway in the placement of the upper intervals. This is often determined by wanting to have a certain note in the top (i.e. the melody) voice. It may also be said that adding doublings of the root (and to a lesser extent the fifth) tend to add "fullness" to the chord without affecting its function or overall character too much.

You should try experimenting with different voicings yourself and see how different ways of arranging the intervals sound to you. Music would be quite boring after all if every chord was arranged strictly in ascending order from the root.